(2,2′-Bi­pyridine-κ2 N,N′)di­chloridopalladium(II) 1,4-dioxane hemisolvate

نویسندگان

  • Ricardo Alfredo Gutiérrez Márquez
  • Carmela Crisóstomo-Lucas
  • David Morales-Morales
  • Simón Hernández-Ortega
چکیده

The asymmetric unit of the title compound, [PdCl2(C10H8N2)]·0.5C4H8O2, consists of one Pd(II) complex mol-ecule and a half-mol-ecule of 1,4-dioxane, the complete mol-ecule being generated by inversion symmetry. The Pd(II) atom has an almost square-planar coordination formed by the 2,2'-bi-pyridine ligand and two chloride ligands. Two intra-molecular C-H⋯Cl hydrogen bonds occur. In the crystal, the Pd(II) complex and 1,4-dioxane mol-ecules are connected by C-H⋯O hydrogen bonds, forming a layer parallel to (10-1). Within the layer, weak π-π inter-actions [centroid-centroid distance = 3.817 (4) Å] are observed between the pyridine rings.

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عنوان ژورنال:

دوره 70  شماره 

صفحات  -

تاریخ انتشار 2014